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Energy absorption potential of concrete floors containing secondary (shrinkage and temperature) reinforcements

K. S. SIVAKUMARAN,R. M. KOROL,Xiao FAN

《结构与土木工程前沿（英文）》 2014年 第8卷 第3期   页码 282-291 doi: 10.1007/s11709-014-0269-3

摘要： This paper experimentally investigates the energy absorption potential of two types of concrete floors, namely, normal density concrete and structural low-density concrete, containing secondary (shrinkage and temperature) reinforcements. The test program considered the following secondary reinforcements: 1) traditional welded-wire steel mesh, 2) steel fiber and 3) poly composite fiber. To estimate the extent to which crushing of floor slab materials would help absorb energy, a series of concrete penetration tests employing patch loading was undertaken on scaled down model slabs. Each concrete-secondary reinforcement combination considered slabs of 50 mm in depth with square plan dimensions ranging from 50 to 500 mm, resulting in a total of 30 test specimens. The first part of the paper discusses the test specimens, the test setup, and the test procedure. The second part of the paper presents the experimental results and establishes the energy absorption of different concrete- secondary reinforcement combinations. Sieve analysis results of the crushed specimens were used to derive a “work index” value that relates the pulverized particle size distributions to energy inputs. The work index values of concrete-secondary reinforcement systems can be used to assess the energy dissipation potential associated with such floor slabs in buildings undergoing progressive collapse. The results indicate that floors with secondary reinforcements could play an important role in helping arrest global progressive collapse.

关键词： concrete floors     structural low-density concrete     shrinkage and temperature reinforcements     energy absorption     penetration tests     sieve analysis    

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Encapsulation of 2-amino-2-methyl-1-propanol with tetraethyl orthosilicate for CO2 capture

Sidra Rama, Yan Zhang, Fideline Tchuenbou-Magaia, Yulong Ding, Yongliang Li

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 672-683 doi: 10.1007/s11705-019-1856-6

摘要： Carbon capture is widely recognised as an essential strategy to meet global goals for climate protection. Although various CO capture technologies including absorption, adsorption and membrane exist, they are not yet mature for post-combustion power plants mainly due to high energy penalty. Hence researchers are concentrating on developing non-aqueous solvents like ionic liquids, CO -binding organic liquids, nanoparticle hybrid materials and microencapsulated sorbents to minimize the energy consumption for carbon capture. This research aims to develop a novel and efficient approach by encapsulating sorbents to capture CO in a cold environment. The conventional emulsion technique was selected for the microcapsule formulation by using 2-amino-2-methyl-1-propanol (AMP) as the core sorbent and silicon dioxide as the shell. This paper reports the findings on the formulated microcapsules including key formulation parameters, microstructure, size distribution and thermal cycling stability. Furthermore, the effects of microcapsule quality and absorption temperature on the CO loading capacity of the microcapsules were investigated using a self-developed pressure decay method. The preliminary results have shown that the AMP microcapsules are promising to replace conventional sorbents.

关键词： carbon capture     microencapsulated sorbents     emulsion technique     low temperature adsorption and absorption    

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Numerical study of a hybrid absorption-compression high temperature heat pump for industrial waste heat

Zhiwei MA, Huashan BAO, Anthony Paul ROSKILLY

《能源前沿（英文）》 2017年 第11卷 第4期   页码 503-509 doi: 10.1007/s11708-017-0515-1

摘要： The present paper aims at exploring a hybrid absorption-compression heat pump (HAC-HP) to upgrade and recover the industrial waste heat in the temperature range of 60°C–120°C. The new HAC-HP system proposed has a condenser, an evaporator, and one more solution pump, compared to the conventional HAC-HP system, to allow flexible utilization of energy sources of electricity and waste heat. In the system proposed, the pressure of ammonia-water vapor desorbed in the generator can be elevated by two routes; one is via the compression of compressor while the other is via the condenser, the solution pump, and the evaporator. The results show that more ammonia-water vapor flowing through the compressor leads to a substantial higher energy efficiency due to the higher quality of electricity, however, only a slight change on the system exergy efficiency is noticed. The temperature lift increases with the increasing system recirculation flow ratio, however, the system energy and exergy efficiencies drop towards zero. The suitable operation ranges of HAC-HP are recommended for the waste heat at 60°C, 80°C, 100°C, and 120°C. The recirculation flow ratio should be lower than 9, 6, 5, and 4 respectively for these waste heat, while the temperature lifts are in the range of 9.8°C–27.7 °C, 14.9°C–44.1 °C, 24.4°C–64.1°C, and 40.7°C–85.7°C, respectively, and the system energy efficiency are 0.35–0.93, 0.32–0.90, 0.25–0.85, and 0.14–0.76.

关键词： absorption compression     high temperature heat pump     efficiency     industrial waste heat     thermodynamic analysis    

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Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomicabsorption spectrometry with a tungsten tube atomizer

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 432-435 doi: 10.1007/s11705-012-1219-z

摘要： In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL ) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver.

关键词： preconcentration     adsorption onto niobium wire     electrothermal atomization atomic absorption spectrometry     tungsten tube atomizer     trace elements    

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A two-stage deep freezing chemisorption cycle driven by low-temperature heat source

Yuanyang HU, Liwei WANG, Lu XU, Ruzhu WANG, Jeremiah KIPLAGAT, Jian WANG

《能源前沿（英文）》 2011年 第5卷 第3期   页码 263-269 doi: 10.1007/s11708-011-0152-z

摘要： A two-stage chemisorption cycle suitable for deep-freezing application driven by low- temperature heat source was proposed. Through two-stage desorption processes, the two-stage cycle can break through the limitations of the heating temperature and ambient cooling temperature. The two-stage cycle based on CaCl /BaCl -NH working pair can utilize the heat source with a temperature of above 75°C, and simultaneously realize deep-freezing all the year round. Experimental results and performance prediction show that the adsorption quantity of calcium, theoretical coefficient of performance (COP) and optimized specific cooling power (SCP) of the CaCl /BaCl -NH chemisorption system are 0.489 kg/kg (salt), 0.24 and 120.7 W/kg, when the heating temperature, ambient cooling temperature, pseudo-evaporating temperature and mass ratio of reacting salt and expanded graphite are 85, 30, -20, and 4∶1, respectively.

关键词： adsorption     freezing     desorption     heat source    

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Integrated adsorption and absorption process for post-combustion CO

Gongkui Xiao, Penny Xiao, Andrew Hoadley, Paul Webley

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 483-492 doi: 10.1007/s11705-020-1964-3

摘要： This study explored the feasibility of integrating an adsorption and solvent scrubbing process for post-combustion CO capture from a coal-fired power plant. This integrated process has two stages: the first is a vacuum swing adsorption (VSA) process using activated carbon as the adsorbent, and the second stage is a solvent scrubber/stripper system using monoethanolamine (30 wt-%) as the solvent. The results showed that the adsorption process could enrich CO in the flue gas from 12 to 50 mol-% with a CO recovery of >90%, and the concentrated CO stream fed to the solvent scrubber had a significantly lower volumetric flowrate. The increased CO concentration and reduced feed flow to the absorption section resulted in significant reduction in the diameter of the solvent absorber, bringing the size of the absorber from uneconomically large to readily achievable domain. In addition, the VSA process could also remove most of the oxygen initially existed in the feed gas, alleviating the downstream corrosion and degradation problems in the absorption section. The findings in this work will reduce the technical risks associated with the state-of-the art solvent absorption technology for CO capture and thus accelerate the deployment of such technologies to reduce carbon emissions.

关键词： vacuum swing adsorption     monoethanolamine     post-combustion     CO2 capture     integrated process    

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膜吸附和膜吸收研究进展

林立刚,叶卉,赵莉芝

《中国工程科学》 2014年 第16卷 第12期   页码 59-66

摘要：

近年来，膜集成过程备受研究者关注，探究传统分离技术与膜技术的结合，充分发挥膜的高效率、易于在线放大等优势，以期促进膜集成过程以低成本实现放大应用。其中，吸附膜、吸收技术兼具膜技术和吸附、吸收技术的优势，在提纯、分离、净化等众多场合获得了日益广泛的应用。本文针对膜吸附、吸收方面的研究，阐述该膜过程研究进展和发展趋势，为相关领域研究人员提供借鉴。

关键词： 膜     膜吸附     膜吸收    

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Experimental study on the temperature dependence of ultraviolet absorption cross-sections of sulfur dioxide

ZHANG Shiliang, ZHOU Jie, CHEN Xiaohu

《能源前沿（英文）》 2008年 第2卷 第2期   页码 183-186 doi: 10.1007/s11708-008-0025-2

摘要： The photoabsorption cross-sections of sulfur dioxide were measured in the spectral regions of 200–230 nm and 275–315 nm at 298–415 K, using a grating monochromator with a resolution of 0.2 nm. The discrete absorption cross-section is directly correlated with the number of quantum excited from the base state. The absorption cross-sections at the peaks of discrete bands decreased linearly with the increase of temperature, which corresponded to the decrease in the population of vibrational and rotational transitions from the base level to higher excitation levels. The absorption cross-section peaks decreased linearly when the temperature increased from 298 to 415 K, with relative drops of 74.0% and 75.8% at 200–230 nm and 275–315 nm, respectively. Another distinctive feature of sulfur dioxide absorption spectra in the above two spectral regions was the quasiperiodic structure of the absorption peaks, whose equal wavelength intervals were 1.53 nm and 1.95 nm, respectively. Red and blue shifts were not found at the absorption peak positions.
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Improving retrieval precision of NO

Jinpeng YANG

《机械工程前沿（英文）》 2009年 第4卷 第1期   页码 92-96 doi: 10.1007/s11465-009-0001-5

摘要： The NO density error retrieved by the traditional method of differential optical absorption spectroscopy (DOAS) was analyzed. The technique for reducing the error is proposed and used to obtain the NO density of Chengdu through DOAS.

关键词： absorption structure     low-frequency structure     absorption cross-section     NO2 density    

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Potassium carbonate-based ternary transition temperature mixture (deep eutectic analogues) for CO absorption

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1500-9

摘要：

•Addition of hindered amine increased thermal stability and viscosity of TTTM.

关键词： Ternary transition-temperature mixture     FT-IR and thermal stability analysis     Viscosity and correlation study     Eyring’s absolute rate theory     CO2 solubility     Density functional theory (DFT).    

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A review of low-temperature plasma-assisted machining: from mechanism to application

《机械工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0734-y

摘要： Materials with high hardness, strength or plasticity have been widely used in the fields of aviation, aerospace, and military, among others. However, the poor machinability of these materials leads to large cutting forces, high cutting temperatures, serious tool wear, and chip adhesion, which affect machining quality. Low-temperature plasma contains a variety of active particles and can effectively adjust material properties, including hardness, strength, ductility, and wettability, significantly improving material machinability. In this paper, we first discuss the mechanisms and applications of low-temperature plasma-assisted machining. After introducing the characteristics, classifications, and action mechanisms of the low-temperature plasma, we describe the effects of the low-temperature plasma on different machining processes of various difficult-to-cut materials. The low-temperature plasma can be classified as hot plasma and cold plasma according to the different equilibrium states. Hot plasma improves material machinability via the thermal softening effect induced by the high temperature, whereas the main mechanisms of the cold plasma can be summarized as chemical reactions to reduce material hardness, the hydrophilization effect to improve surface wettability, and the Rehbinder effect to promote fracture. In addition, hybrid machining methods combining the merits of the low-temperature plasma and other energy fields like ultrasonic vibration, liquid nitrogen, and minimum quantity lubrication are also described and analyzed. Finally, the promising development trends of low-temperature plasma-assisted machining are presented, which include more precise control of the heat-affected zone in hot plasma-assisted machining, cold plasma-assisted polishing of metal materials, and further investigations on the reaction mechanisms between the cold plasma and other materials.

关键词： low-temperature plasma     difficult-to-cut material     machinability     hydrophilization effect     Rehbinder effect    

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Investigation on the performance and detoxification of modified low temperature coal tar pitch

Fengyan SUN, Yu LIU

《结构与土木工程前沿（英文）》 2017年 第11卷 第3期   页码 315-321 doi: 10.1007/s11709-017-0386-x

摘要： In this paper, studies on the modification on the low temperature coal tar pitch extracted from coal tar residue in Inner Mongolia are conducted. First, the low temperature coal tar pitch in liquid state is solidified with a higher softening point by chemical crosslinking modification. The modified coal tar pitch can achieve the standard pavement performance requirements. Then, the effects of chemical crosslinking agent and physical modification additives on the mechanical performance and toxic properties of coal tar pitch are investigated. The detoxification mechanism is also studied, which further promote the applicability of modified low temperature coal tar pitch in the pavement constructions.

关键词： coal tar pitch     low temperature     modification     detoxification    

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A review on the development of electrolytes for lithium-based batteries for low temperature applications

《能源前沿（英文）》 2023年 第17卷 第1期   页码 43-71 doi: 10.1007/s11708-022-0853-5

摘要： The aerospace industry relies heavily on lithium-ion batteries in instrumentation such as satellites and land rovers. This equipment is exposed to extremely low temperatures in space or on the Martian surface. The extremely low temperatures affect the discharge characteristics of the battery and decrease its available working capacity. Various solvents, cosolvents, additives, and salts have been researched to fine tune the conductivity, solvation, and solid-electrolyte interface forming properties of the electrolytes. Several different resistive phenomena have been investigated to precisely determine the most limiting steps during charge and discharge at low temperatures. Longer mission lifespans as well as self-reliance on the chemistry are now highly desirable to allow low temperature performance rather than rely on external heating components. As Martian rovers are equipped with greater instrumentation and demands for greater energy storage rise, new materials also need to be adopted involving next generation lithium-ion chemistry to increase available capacity. With these objectives in mind, tailoring of the electrolyte with higher-capacity materials such as lithium metal and silicon anodes at low temperatures is of high priority. This review paper highlights the progression of electrolyte research for low temperature performance of lithium-ion batteries over the previous several decades.

关键词： electrolyte     lithium-ion     low temperature     aerospace     solid-electrolyte interface    

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Simulation on thermodynamic state of ammonia carbonation at low temperature and low pressure

Jingcai ZHAO, Xingfu SONG, Ze SUN, Jianguo YU

《化学科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 447-455 doi: 10.1007/s11705-013-1370-1

摘要： This study on thermodynamic property of NH -CO -H O system provided the basic data for ammonia carbonation. Simulations on vapor-liquid equilibrium (VLE) of ammonia carbonation with different physical properties were discussed in NH -H O and NH -CO -H O systems, respectively. The results indicated that at low temperature (303.15 K–363.15 K) and pressure (0.1–0.4 MPa), the PR (Peng-Robinson) equation was suitable for the description of the thermodynamic state in NH -H O system. NRTL (Non-Random-Two-Liquid) series models were selected for NH -CO -H O mixed electrolyte solution system. VLE data regression results showed that NRTL series models were suitable for describing thermodynamic properties of NH -CO -H O system, because average relative error fitting with each model was about 1%. As an asymmetric electrolytes model in NRTL model, E–NRTLRK (Electrolyte NRTL Redlich Kwong) could most accurately fit VLE data of NH -CO -H O system, with fitting error less than 1%. In the extent temperature range of 273.15 K–363.15 K, the prediction of product component using E-NRTLRK model for ammonia carbonation agreed well with the data reported in literature.

关键词： vapor-liquid equilibrium     activity coefficient     carbon dioxide     ammonia     NRTL    

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Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 277-283 doi: 10.1007/s11783-013-0562-8

摘要： Polychlorinated biphenyls PCBs) were removed by low-temperature plasma technique (dielectric barrier discharge) from heavily polluted soil and their intermediate products were analyzed. The removal rate ranged from 40.1 to 84.6% by different treatments, and they were also influenced significantly ( <0.01) by soil particle-size, electric power, gas flow rate and reaction time. The optimal reaction conditions of PCB removal from the soil were obtained experimentally when soil particle-size, electrical power, flow rate and reaction time were 5–10 mm, 21 w, 120 mL· min and 90 min, respectively. However, decreasing electrical power, flow rate and reaction time to 18 w, 60 mL· min and 60 min respectively were also acceptable in view of the cost of remediation. This technique was characterized by the additional advantage of thorough oxidation of PCBs in the soil, with no formation of intermediate products after reaction. The technique therefore shows some promise for application in the remediation of soils contaminated with persistent organic pollutants in brown field sites in urban areas.

关键词： polychlorinated biphenyls     low-temperature plasma     soil contamination     intermediate products    

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标题 作者 时间 类型 操作

Energy absorption potential of concrete floors containing secondary (shrinkage and temperature) reinforcements

K. S. SIVAKUMARAN,R. M. KOROL,Xiao FAN

期刊论文

Encapsulation of 2-amino-2-methyl-1-propanol with tetraethyl orthosilicate for CO2 capture

Sidra Rama, Yan Zhang, Fideline Tchuenbou-Magaia, Yulong Ding, Yongliang Li

期刊论文

Numerical study of a hybrid absorption-compression high temperature heat pump for industrial waste heat

Zhiwei MA, Huashan BAO, Anthony Paul ROSKILLY

期刊论文

Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomicabsorption spectrometry with a tungsten tube atomizer

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

期刊论文

A two-stage deep freezing chemisorption cycle driven by low-temperature heat source

Yuanyang HU, Liwei WANG, Lu XU, Ruzhu WANG, Jeremiah KIPLAGAT, Jian WANG

期刊论文

Integrated adsorption and absorption process for post-combustion CO

Gongkui Xiao, Penny Xiao, Andrew Hoadley, Paul Webley

期刊论文

膜吸附和膜吸收研究进展

林立刚,叶卉,赵莉芝

期刊论文

Experimental study on the temperature dependence of ultraviolet absorption cross-sections of sulfur dioxide

ZHANG Shiliang, ZHOU Jie, CHEN Xiaohu

期刊论文

Improving retrieval precision of NO

Jinpeng YANG

期刊论文

Potassium carbonate-based ternary transition temperature mixture (deep eutectic analogues) for CO absorption

期刊论文

A review of low-temperature plasma-assisted machining: from mechanism to application

期刊论文

Investigation on the performance and detoxification of modified low temperature coal tar pitch

Fengyan SUN, Yu LIU

期刊论文

A review on the development of electrolytes for lithium-based batteries for low temperature applications

期刊论文

Simulation on thermodynamic state of ammonia carbonation at low temperature and low pressure

Jingcai ZHAO, Xingfu SONG, Ze SUN, Jianguo YU

期刊论文

Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

期刊论文